黔西南中晚二叠世大厂层火山热水沉积成矿作用     

杜丽娟  陈军  杨瑞东  黄智龙  郑禄林  高军波  魏怀瑞 《地质论评》2020,66(2):439-456

贵州晴隆大厂锑矿区赋矿地层大厂层为一套以硅化为主的火山碎屑岩沉积建造,因其别具特色的岩石组合、特殊的构造位置,以及含有金、锑、萤石、硫铁矿等矿产资源而备受地学界关注。晴隆大厂锑矿床90%以上的锑矿体和金矿化体均位于大厂层之中,因此,研究大厂层的形成和演化过程及其对锑、金成矿的控制作用或影响机理显得尤为重要。沉积岩相学研究表明,大厂层主要包括火山岩相(火山溢流相、淬碎角砾岩相、沉凝灰岩相、空落集块岩相和熔结凝灰岩相)和热液沉积岩相(热水沉积相、热水喷流相和热水交代相)。中—晚二叠世(约260 Ma)的溢流玄武岩、基性火山喷发和海底热水喷流活动是大厂层的主要物源供给者。元素地球化学研究表明,大厂层在沉积过程的热水喷流沉积作用提供了Sb、As、Au、Ag、Pb等成矿元素,并形成成矿元素的初始"富集体"。综合研究认为,中—晚二叠世的热水喷流沉积活动在时间上与右江盆地印支期低温热液成矿事件(200～250 Ma)在时空上基本一致,为印支期成矿事件在右江盆地北缘的响应。  相似文献   

大凌河河口地区中更新世晚期以来沉积环境演化     

商志文  李建芬  姜兴钰  李琰  王宏 《地质学报》2020,94(8):2433-2445

大凌河河口地区LZK06孔40m以浅岩心的沉积学、古生物学和年代学等综合研究以及该地区LZK02- 04钻孔资料，揭示了研究区中更新世晚期以来经历了两次海侵- 海退旋回，依次形成了中更新世晚期湖相/河流相 SymbolnB@ 晚更新世海相- 湖相/河流相 SymbolnB@ 全新世海相- 河流相地层。全新世早中期由于物源供给很少，研究区处于长达约10ka的饥饿滞留相沉积环境，平均沉积速率仅约0. 02~0. 05cm/a。全新世晚期约1500a cal BP以来，由于人类活动导致水土流失，河流输砂量增加，研究区开始了快速加积过程，平均沉积速率约0. 9~1. 2cm/a，下辽河平原被快速充填，开始成陆。与全球海面变化时空分布特征的对比，推断辽东湾的第II海相层发育于MIS 5- MIS 3早期，第I海相层发育于MIS 1阶段高海面时期。晚更新世以来频繁的海面升降是辽东湾泥质海岸带地层和环境演化的主要控制因素。  相似文献   

新疆北部弧-盆转化体系下铁氧化物-铜-金矿床的流体演化特征:来自卤族元素和稀有气体同位素的证据     

梁培  陈华勇  赵联党  Kendrick MARK  江宏君  张维峰  吴超  谢玉玲 《地学前缘》2020,27(3):239-253

东准噶尔北缘和东天山雅满苏带是中国新疆北部地区两个重要的晚古生代铁氧化物-铜-金矿化潜力区,以老山口、乔夏哈拉和黑尖山矿床作为典型矿床代表。研究表明两区域的铁氧化物-铜-金矿床均产出于盆地闭合的弧盆转化体系下,且具有明显的铁、铜-金两阶段矿化。卤族元素和稀有气体同位素作为可靠的流体示踪剂,被应用于探究这一特定构造环境下的铁氧化物-铜-金矿床的流体演化和矿床成因。结果显示老山口、乔夏哈拉和黑尖山矿床的成矿流体具有明显的混合流体端员特征:(1)岩浆流体端员,主要参与黑尖山矿床磁铁矿阶段,I/Cl、Br/Cl和⁴⁰Ar/³⁶Ar比值分别为(16.3~18.0)×10^-6、(1.03~1.06)×10^-3和352~437;(2)海水表源蒸发成因盐卤水端员,主要参与老山口矿床铜-金矿化阶段,I/Cl、Br/Cl和⁴⁰Ar/³⁶Ar比值分别为(77.1~87.7)×10^-6、(1.53~1.80)×10^-3和672~883;(3)蒸发岩溶解或者深度水-岩反应成因的盐卤水/沉积岩地层水端员,主要参与到老山口、乔夏哈拉矿床的磁铁矿阶段以及黑尖山、乔夏哈拉矿床的铜-金矿化阶段,综合I/Cl、Br/Cl和⁴⁰Ar/³⁶Ar比值分别为(477~26 301)×10^-6、(0.39~1.28)×10^-3和288~510。明显的多阶段矿化和铜-金矿化阶段以非岩浆富Ca高盐度卤水为主的特征与世界范围内的IOCG型矿床极为相似,表明新疆北部的铁氧化物-铜-金矿床应为IOCG型矿床。  相似文献   

Microstructure Evolution of Organic Matter and Clay Minerals in Shales with Increasing Thermal Maturity     

GU Yuantao  LI Xiaoxi  YANG Shuguang  WAN Quan 《《地质学报》英文版》2020,94(2):280-289

As the two important components of shale, organic matter(OM) and clay minerals are usually thought to strongly influence the hydrocarbon generation, enrichment and exploitation. The evolution process of OM and clay minerals as well as their interrelationship over a wide range of thermal maturities are not completely clear. Taking Yanchang(T_3y), Longmaxi(S_1l) and Niutitang(?_1n) shales as examples, we have studied the microstructure characteristics of OM and clay minerals in shales with different thermal maturities. The effects of clay minerals and OM on pores were reinforced through sedimentation experiments. Using a combination of field emission scanning electron microscopy(FESEM) and low-pressure N_2 adsorption, we investigated the microstructure differences among the three shales. The results showed that both OM and clay minerals have strong effects on pores, and small mesopore(2–20 nm) is the dominant pore component for all three samples. However, the differences between the three samples are embodied in the distribution of pore size and the location. For the T_3y shale, clay minerals are loosely arranged and develop large amounts of pores, and fine OM grains often fill in intergranular minerals or fractures. Widespread OM pores distribute irregularly in S_1l shale, and most of the pores are elliptical and nondirectional. The ?_1n shale is characterized by the preferred orientational OM-clay aggregates, and lots of pores in the composites are in the mesopore range, suggesting that over maturity lead to the collapse and compaction of pores under huge pressure of strata. The results of the current research imply that with increasing thermal maturity, OM pores are absent at low maturity(T_3y), are maximized at high maturity(S_1l) and are destroyed or compacted at over-mature stage(?_1n). Meanwhile, clay minerals have gone through mineral transformation and orientational evolution. The interaction of the two processes makes a significant difference to the microstructure evolution of OM and clay minerals in shale, and the findings provide scientific foundation in better understanding diagenetic evolution and hydrocarbon generation of shale.  相似文献   

Nature and Evolution of Pre-Neoproterozoic Continental Crust in South China: A Review and Tectonic Implications     

WANG Kai  DONG Shuwen  YAO Weihu  ZHAO Tianyu 《《地质学报》英文版》2020,94(6):1731-1756

South China as an amalgamation of the Yangtze and Cathaysia blocks is composed of Archean to Mesoproterozoic basement overlain by Neoproterozoic and younger cover. Both the constituent Yangtze and Cathaysia blocks contain well-preserved Neoproterozoic rocks that have been extensively studied in terms of the age and tectonic nature, but less is known about their earlier crustal history due to the incomplete rock record. Recent efforts in investigating the yet survived crustal nature based on isotopic and elemental signatures preserved in igneous and sedimentary rocks have steadily improved our knowledge about the pre-Neoproterozoic continental crustal evolution in South China. In this paper, we summarize the up-to-date pre-Neoproterozoic records, including petrological, geochronological, geochemical and geophysical data, across South China, and discuss its spatiotemporal patterns of the pre-Neoproterozoic crust and the relevant tectonic events. While the xenocrystic/inherited and detrital zircon records suggest widespread Archean (mainly ca. 2.5 Ga) crustal components within both the Yangtze and Cathaysia blocks, exposed Archean rocks are only limited to isolated crustal provinces in the Yangtze Block. These Archean rocks are dominated by TTGs (tonalite-trondhjemite-granodiorite) with varied ages (3.3–2.5 Ga) and zircon Hf isotopes, indicating a compositionally heterogeneous nature of the Archean Yangtze Block and, by inference, the development of multiple ancient terranes. The early Paleoproterozoic (2.4–2.2 Ga) tectonomagmatic events characterize the western Yangtze Block and are supportive of an east-west subdivision of the Yangtze basement, whereas the late Paleoproterozoic (2.1–1.7 Ga) orogeneses may have affected a larger area covering both the western and eastern parts of the Yangtze Block, and also the Cathaysia Block. The eastern Yangtze Block with generally northeastward-younging late Paleoproterozoic magmatism and metamorphism likely experienced a prolonged 2.05–1.75 Ga orogenic process welding the various Archean proto-continents, consistent with the documentation of a buried late Paleoproterozoic orogenic belt imaged by deep seismic profiling from its central part and of a slightly older ophiolitic mélange in the northern part. The Cathaysia Block was probably involved in a short-lived 1.9–1.8 Ga orogenic event. The two orogeneses overlapped in time and may have contributed to the cratonization of a possible unified South China, and are referred to be linked with the assembly of the Nuna Supercontinent. The subsequent late Paleoproterozoic to early Mesoproterozoic rift successions and intrusions (1.7–1.5 Ga) in the southwestern Yangtze Block, and the ca. 1.43 Ga rifting in Hainan Island of the Cathaysia Block could be responses to the Nuna break-up. Late Mesoproterozoic (1.2–1.0 Ga) magmatism of varied age and nature in different localities of the Yangtze Block is reflective of a complex tectonic process in the context of the assembly of the Rodinia Supercontinent. Similar-aged metamorphism (1.3–1.0 Ga) is recorded in Hainan Island, reflecting the Grenvillian continental collision during the Rodinia assembly, but further studies are necessary to better constrain the late Mesoproterozoic tectonic framework of South China.  相似文献   

海南典型热带海草床4种代表性鱼类的生长特征及其对海草资源量变化的响应     

陈启明  刘松林  张弛  崔黎军  江志坚  吴云超  黄小平 《热带海洋学报》2020,39(5):62-70

文章以海南岛新村湾、黎安港和潭门港海草床为研究区域, 选取褐篮子鱼(Siganus fuscessens)、点斑篮子鱼(Siganus guttatus)、四带牙鯻(Pelates quadrilineatus)和细鳞鯻(Terapon jarbua) 4种代表性鱼类为研究对象, 分析其体长与体质量的关系, 并探讨4种鱼类对海草资源量变化的响应。结果表明, 除栖息于潭门港海草床的4种鱼为负异速生长, 其他区域海草床的鱼类均为正异速或等速生长; 4种鱼的体质量生长速率(即异速生长因子b)和肥满度呈现黎安港>新村湾>潭门港的趋势, 并与3个海草床的海草覆盖率、密度和生物量的变化趋势一致; 推测海草资源量下降可能增加鱼类的被捕食压力和减少食物来源, 从而导致生活于海草床的代表性鱼类生长速率下降。  相似文献   

NaHSO3对两种微藻生长及胞外多糖和藻胆蛋白含量的影响     

梁英  闫译允  黄徐林  田传远  胡乃霞  王帅 《中国海洋大学学报(自然科学版)》2020,(1):21-29

本文研究了0.25~3 mmol/L浓度的NaHSO3对紫球藻(Porphyridium violaceum)和0.06~0.96 mmol/L浓度的NaHSO3对蓝隐藻(Chroomonas placoidea)的叶绿素荧光参数(PSII最大光能转化效率Fv/Fm、相对电子传递速率rETR、光化学淬灭qP、非光化学淬灭NPQ)、细胞密度、干重、胞外多糖和藻胆蛋白含量的影响。研究表明,较低浓度的NaHSO3对紫球藻和蓝隐藻的生长及活性物质积累有促进作用,2种微藻进行生长和活性物质积累的最适NaHSO3浓度分别为0.5和0.12 mmol/L,此条件下,实验结束时,2种微藻的Fv/Fm、rETR、qP、细胞密度、干重、胞外多糖和藻胆蛋白含量均达到最大值,显著高于对照组。其中,紫球藻的最终细胞密度、干重、胞外多糖和藻胆蛋白含量分别比对照组增加了36.0%、19.1%、71.8%和69.0%。蓝隐藻的上述参数在NaHSO3浓度为0.12 mmol/L时则比对照组增加了60.8%、45.4%、60.0%和53.1%。另一方面,NaHSO3浓度为2~3 mmol/L时显著抑制紫球藻生长及活性物质积累,NaHSO3浓度为0.48~0.96 mmol/L则不利于蓝隐藻生长及活性物质积累。研究结果表明,适合紫球藻和蓝隐藻生长及胞外多糖和藻胆蛋白积累的最佳NaHSO3浓度分别为0.5和0.12 mmol/L,该研究为2种微藻的开发利用提供了理论依据。  相似文献   

琼东南盆地华光凹陷天然气水合物稳定带厚度的影响因素     

刘杰  杨睿  邬黛黛  金光荣  张辉 《海洋学报》2019,41(8):13-25

为了探讨琼东南盆地华光凹陷海底天然气水合物稳定带的分布规律，定量研究了静水压力、底水温度、地温梯度和气源组分对水合物稳定带的影响程度。在此基础上，分析了华光凹陷现今甲烷水合物稳定带的厚度分布。最后，综合各因素的历史演化过程，初步探讨了华光凹陷1.05 Ma BP以来天然气水合物稳定带的演化。结果表明:(1)气源组分和海底温度的变化对研究区内水合物稳定带的影响较大；水合物稳定带厚度与海底温度呈良好的线性负相关性。(2)水深超过600 m的海域具备形成天然气水合物的温压条件；超过600 m水深的海域水合物稳定带厚度大部分超过 100 m，其中西北部稳定带的最大厚度超过300 m，是有利的水合物勘探区。(3)华光凹陷1.05 Ma BP以来天然气水合物稳定带厚度经历了快速增厚–窄幅变化–快速减薄和恢复的过程。麻坑群与水合物稳定变化敏感区在空间上具有较好的叠合关系。结合前人的研究成果，推测其形成与天然气水合物的分解释放有关。  相似文献   

Clinoform growth and sediment flux into late Cenozoic Qiongdongnan shelf margin,South China Sea     

Si Chen  Ronald Steel  Hua Wang  Rui Zhao  Cornel Olariu 《Basin Research》2020,32(2):302-319

The South China Sea continental margin in the Qiongdongnan Basin (QDNB) area has incrementally prograded since 10.5 Ma generating a margin sediment prism more than 4km-thick and 150–200 km wide above the well-dated T40 stratigraphic surface. Core and well log data, as well as clinoform morphology and growth patterns along 28 2D seismic reflection lines, illustrate the evolving architecture and margin morphology; through five main seismic-stratigraphic surfaces (T40, T30, T27, T20 and T0) frame 15 clinothems in the southwest that reduce over some 200 km to 8 clinoforms in the northeast. The overall margin geometry shows a remarkable change from sigmoidal, strongly progradational and aggradational in the west to weakly progradational in the east. Vertical sediment accumulation rate increased significantly across the entire margin after 2.4 Ma, with a marked increase in mud content in the succession. Furthermore, an estimate of sediment flux across successive clinoforms on each of the three selected seismic cross sections indicate an overall decrease in sediment discharge west to east, away from the Red River depocenter, as well as a decrease in the percentage of total discharge crossing the shelf break in this same direction. The QDNB Late Cenozoic continental margin growth, with its overall increased sediment flux, responded to the climate-induced, gradual cooling and falling global sea level during this icehouse period.  相似文献   

Mineralogy,Fluid Inclusion,and Hydrogen and Oxygen Isotope Studies of the Intrusion‐Related Yangla Cu Deposit in the Sanjiang Region,SW China: Implications for Metallogenesis and Deposit Type     

Li‐Juan Du  Bo Li  Zhi‐Long Huang  Jun Chen  Jia‐Xi Zhou  Guo‐Fu Zou  Zai‐Fei Yan 《Resource Geology》2020,70(1):28-49

The Yangla deposit is an intrusion‐related Cu deposit in the Jinshajiang tectonic belt (eastern Sanjiang region, SW China). Despite extensive studies that have been conducted on this deposit, the relationship between the granitic magma and Cu mineralization is still unclear, and hence, the genesis is debated. To answer this question, we conducted an integrated study of mineralogy, fluid inclusions (FIs), and hydrogen and oxygen (H‐O) isotopes. Three mineralization stages were identified based on the ore textures, alteration zonation, and crosscutting relationships: (i) pre‐ore prograde skarn (stage I), with the garnet and pyroxene dominated by andradite and diopside, respectively; (ii) syn‐ore retrograde alteration (stage II), which is subdivided into the early syn‐ore stage (stage IIa) marked by retrograde hydrated mineral assemblages and significant Fe‐Cu‐Mo‐Pb‐Zn sulfide mineralization, and the late syn‐ore stage (stage IIb) featured by quartz‐calcite veins; and (iii) late supergene mineralization (stage III), which is characterized by secondary azurite and malachite. These results of mineralogy, FIs, and H‐O isotopes indicate that: (i) Cu mineralization has a close temporal, spatial, and genetic relationship with skarn alteration; (ii) the ore fluids were magmatic dominated with late‐stage meteoric water incursion; and (iii) Type‐S (halite‐bearing) and Type‐V (vapor‐rich) FIs coexisted in garnet and clinopyroxene of stage I, indicating that fluid boiling might have occurred during this stage. From stage I to stage IIa, the FI type transformed from Type‐S + Type‐V + Type‐L (liquid‐rich) to Type‐V + Type‐L with the conduct of mineralization and was accompanied by the disappearance of Type‐S, and homogenization temperature and salinity also tended to decrease dramatically, which may be caused by the deposition of skarn minerals. At stage IIa, boiling of the ore fluids still continued due to the change from lithostatic to hydrostatic pressure, which triggered the precipitation of abundant quartz‐Cu‐Mo‐Fe sulfides. Furthermore, fluid mixing between a high‐temperature magmatic fluid and a low‐temperature meteoric water might cause a considerable drop in temperature and the deposition of Cu‐bearing quartz/calcite veins during stage IIb. Hence, we consider the Yangla deposit to be of a skarn type, genetically related to the Mesozoic magmatism in the Sanjiang region.  相似文献